Реакция #75212

ord-50e155d1b07345909d06eb70052e19d5

Уравнение реакции

CSCC(SC(=O)c1ccccc1)C(=O)N1CCC[C@H]1C(=O)O
1-[2-benzoylthio-3-(methylthio)propanoyl]-L-proline
CSCC(CSC(C)=O)C(=O)N1CCC[C@H]1C(=O)O
1-[3-acetylthio-2-(methylthiomethyl)propanoyl]-L-proline
→
CSCC(S)C(=O)N1CCC[C@H]1C(=O)O
1-[2-mercapto-3-(methylthio)propanoyl]-L-proline

Реактанты

CSCC(SC(=O)c1ccccc1)C(=O)N1CCC[C@H]1C(=O)O
1-[2-benzoylthio-3-(methylthio)propanoyl]-L-proline
CSCC(CSC(C)=O)C(=O)N1CCC[C@H]1C(=O)O
1-[3-acetylthio-2-(methylthiomethyl)propanoyl]-L-proline

Реагенты

Нет

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Методика

By substituting 1-[2-benzoylthio-3-(methylthio)propanoyl]-L-proline for the 1-[3-acetylthio-2-(methylthiomethyl)propanoyl]-L-proline in the procedure of Example 17, 1-[2-mercapto-3-(methylthio)propanoyl]-L-proline is obtained.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US04175199uspto-grants-1979_11