Реакция #74963

Уравнение реакции

Hexachlorocyclopentadiene

tert-butyl-p-benzoquinone

→

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

Растворители

toluene

Условия реакции

Обработка

1. 1
   ПромывкаThe solid was washed with methanol
2. 2
   Другоеrecrystallized from benzene
3. 3
   ДругоеYellow crystals were obtained melting at 124°-125° C.

Методика

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

Источник