Реакция #705652
ord-ef2b8b062e574118974b4c3a1d4f8eac
Уравнение реакции
trimethylsulfonium
trimethylsulfonium iodide
carbon dioxide
hydrogen peroxide
N-phosphonomethylglycine
→
trimethylsulfonium hydroxide
carbon dioxide
iodine (ii)
Реактанты
Реагенты
Нет
Условия реакции
Подробные условия
See reaction.notes.procedure_details.
Методика
A process for the manufacture of the trimethylsulfonium salt of N-phosphonomethylglycine which comprises (i) reacting trimethylsulfonium iodide, hydrogen peroxide and carbon dioxide to form trimethylsulfonium hydroxide and free iodine (ii) reacting the resultant solution with gaseous carbon dioxide to form trimethylsulfonium carbonate or bicarbonate or a mixture thereof (iii) optionally obtaining the trimethylsulfonium bicarbonate or carbonate or the mixture thereof as a transportable solid or a concentrated aqueous solution, and (v) reacting N-phosphonomethylglycine with an aqueous solution of trimethylsulfonium bicarbonate or carbonate or the mixture thereof.