Реакция #65939

ord-75bbb72c1611455996c21d6d6c495e0c

Уравнение реакции

CCCN(C(C)C)C1CSc2cccc(-c3ccccc3)c2C1.Cl
3-(N-Isopropyl-N-n-propylamino)-5-phenylthiochroman hydrochloride
O=C(OO)c1cccc(Cl)c1
m-chloroperbenzoic acid
→
CCCN(C(C)C)C1Cc2c(-c3ccccc3)cccc2S(=O)C1
3-(N-Isopropyl-N-n-propylamino)-5-phenyl-1-oxothiochroman

Реактанты

CCCN(C(C)C)C1CSc2cccc(-c3ccccc3)c2C1.Cl
3-(N-Isopropyl-N-n-propylamino)-5-phenylthiochroman hydrochloride
O=C(OO)c1cccc(Cl)c1
m-chloroperbenzoic acid

Реагенты

Нет

Растворители

ClC(Cl)Cl
chloroform

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    workup.ADDITIONadded in one portion

Методика

3-(N-Isopropyl-N-n-propylamino)-5-phenylthiochroman hydrochloride (310 mg, 0.86 mmol) was dissolved in 6 mL chloroform and to the cooled solution (ice-bath) was m-chloroperbenzoic acid (348 mg, 1.72 mmol) added in one portion.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US05420151uspto-grants-1995_05