Реакция #64045

ord-a4ba08a8042b4ca1951bdb95b8c8499a

Уравнение реакции

CCC(=O)C1=C(O)CC(c2c(C)cc(C)cc2C)CC1=O
3-hydroxy-5-mesityl-2-propionylcyclohex-2-en-1-one
O=S(=O)(O)Cl
chlorosulfonic acid
CNC
dimethylamine
CCON.Cl
ethoxyamine hydrochloride
→
CCON=C(CC)C1=C(O)CC(c2c(C)cc(C)c(S(=O)(=O)N(C)C)c2C)CC1=O
2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-dimethylsulfamoylphenyl)cyclohex-2-en-1-one

Реактанты

CCC(=O)C1=C(O)CC(c2c(C)cc(C)cc2C)CC1=O
3-hydroxy-5-mesityl-2-propionylcyclohex-2-en-1-one
O=S(=O)(O)Cl
chlorosulfonic acid
CNC
dimethylamine
CCON.Cl
ethoxyamine hydrochloride

Реагенты

Нет

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Методика

2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-dimethylsulfamoylphenyl)cyclohex-2-en-1-one (11) was prepared from 3-hydroxy-5-mesityl-2-propionylcyclohex-2-en-1-one, chlorosulfonic acid, dimethylamine, and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 5.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US04767879uspto-grants-1988_08