Реакция #587515

Уравнение реакции

cyclohexylsulfonamide

neopentylmagnesium chloride

→

desired product

Выход 27.0%

Neopentylsulfonamide

Выход 27.0%

Растворители

diethyl ether

Условия реакции

Методика

Following the procedure for the preparation of cyclohexylsulfonamide, 49 mL (37 mmol) of 0.75M neopentylmagnesium chloride (Alfa) in diethyl ether was converted to 1.52 g (27%) of the desired product as a white solid. 1H NMR (CDCl3) δ 1.17 (s, 9H), 3.12 (s, 2H), 4.74 (brs, 2H); 13C NMR (CDCl3) δ 29.46, 31.51, 67.38; MS m/e 150 (M−1)−.

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