Реакция #54883

Уравнение реакции

1-(2-Tetrahydropyranyloxy)-4-acetoxy-5-propoxy-2-pentyne

hydrogen

→

title compound

1-(2-Tetrahydropyranyloxy)-4-acetoxy-5-propoxypentane

Растворители

ethyl acetate

Условия реакции

Обработка

1. 1
   Другое/in2 and 25° C
2. 2
   Другоеthe catalyst is removed by filtration
3. 3
   Другоеthe solvent is evaporated under vacuum

Методика

1-(2-Tetrahydropyranyloxy)-4-acetoxy-5-propoxy-2-pentyne (10.8 g., 0.04 mole) is dissolved in ethyl acetate (100 ml.). 5% Palladium on carbon is added and the mixture is hydrogenated on the Parr apparatus at an initial pressure of 41 lbs./in2 and 25° C. When 0.08 mole of hydrogen is absorbed, the catalyst is removed by filtration and the solvent is evaporated under vacuum to give the title compound as a light orange residual oil.

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