Реакция #547581

ord-6fffa5eb327f4108a8cf3204e8854c1c

Уравнение реакции

CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[K+]
potassium oleate
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucose
O=P([O-])([O-])OP(=O)([O-])[O-].[Na+].[Na+].[Na+].[Na+]
sodium pyrophosphate
C=CC=C
butadiene
C=Cc1ccccc1
styrene
O=S(=O)(O)O
sulfuric acid
C=CC#N
acrylonitrile
→
C=CC#N.C=CC=C.C=Cc1ccccc1
acrylonitrile-butadiene-styrene

Реактанты

—
mercaptan
—
ferrous sulfate hydrate
CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[K+]
potassium oleate
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucose
O=P([O-])([O-])OP(=O)([O-])[O-].[Na+].[Na+].[Na+].[Na+]
sodium pyrophosphate
C=CC=C
butadiene
C=Cc1ccccc1
styrene
O=S(=O)(O)O
sulfuric acid
C=CC#N
acrylonitrile

Реагенты

Нет

Растворители

O
water

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    workup.ADDITIONwere added
  2. 2
    Другоеto obtain g-ABS latex
  3. 3
    Другоеdried

Методика

50 parts of butadiene rubber latex powder, 36 parts of styrene, 14 parts of acrylonitrile, and 150 parts of deionized water were blended. To the blend, 1.0 parts of potassium oleate, 0.4 parts of cumenhydroperoxide, 0.2 parts of mercaptan-containing chain transfer agent, 0.4 parts of glucose, 0.01 parts of ferrous sulfate hydrate, and 0.3 parts of sodium pyrophosphate were added. The blend was kept at 75° C. for 5 hours to obtain g-ABS latex. To the g-ABS latex, 0.4 parts of sulfuric acid was added, coagulated and dried to obtain acrylonitrile-butadiene-styrene graft copolymer resin (g-ABS) in a powder form.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US07196126B2uspto-grants-2007_03