Реакция #527379

ord-35e7ccac4c224c71a3f4de7f53a9270b

Уравнение реакции

OCCCCCCCCCCCCBr
12-bromo-1-dodecanol
CCCCCCCCCCCCCCCCCCSc1ccc(C=Cc2ccc(S(=O)(=O)CCCCCCCCO)cc2)cc1
4-octadecylthio-4'-[(1-hydroxy)-8-octylsulfonyl]stilbene
Cc1ccc(S(=O)(=O)CCCOC2CCCCO2)cc1
2a
Cc1ccc(S(=O)(=O)CCCOC2CCCCO2)cc1
3-(4-Methylphenyl)sulfonyl-1-tetrahydropyranyloxypropane
→
Cc1ccc(S(=O)(=O)CCCCCCCCCCCCOC2CCCCO2)cc1
12-(4-methylphenyl)sulfonyl-1-tetrahydropyranyloxydodecane

Реактанты

OCCCCCCCCCCCCBr
12-bromo-1-dodecanol
CCCCCCCCCCCCCCCCCCSc1ccc(C=Cc2ccc(S(=O)(=O)CCCCCCCCO)cc2)cc1
4-octadecylthio-4'-[(1-hydroxy)-8-octylsulfonyl]stilbene
—
4n
Cc1ccc(S(=O)(=O)CCCOC2CCCCO2)cc1
2a
Cc1ccc(S(=O)(=O)CCCOC2CCCCO2)cc1
3-(4-Methylphenyl)sulfonyl-1-tetrahydropyranyloxypropane

Реагенты

Нет

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Методика

4-octadecylthio-4'-[(1-hydroxy)-8-octylsulfonyl]stilbene. 4n) As described in Examples 1a and 2a 12-bromo-1-dodecanol gives 12-(4-methylphenyl)sulfonyl-1-tetrahydropyranyloxydodecane. Using this compound similarly gives:

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US05517350uspto-grants-1996_05