Реакция #521672

ord-14aa05a9e70445bf9970977a891a1384

Уравнение реакции

OB(O)O
boric acid
O=C([O-])[C@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[Na+]
sodium glucoheptonate
→
O=C(O)[C@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucoheptonic acid

Реактанты

OB(O)O
boric acid
O=C([O-])[C@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[Na+]
sodium glucoheptonate

Реагенты

Нет

Растворители

O
water
O
water

Условия реакции

Температура
25°CELSIUS
Подробные условия
See reaction.notes.procedure_details.

Методика

The diboron ester of glucoheptonic acid was prepared as follows: Approximately 124 grams (2 mols) of boric acid and 248 grams (1 mol) of sodium glucoheptonate were charged to an esterification vessel containing about 600 milliliters of water as a solvent. With stirring, the temperature was maintained at about 25° C. for approximately 30 minutes. The mixture was thereafter diluted to a final volume of one liter with additional water.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US04397812uspto-grants-1983_08