Реакция #50708

Уравнение реакции

8-phenyloctyl chloride

sodium iodide

→

8-phenyloctyl iodide

Растворители

acetone

Условия реакции

Обработка

1. 1
   Температураwas heated
2. 2
   Температураunder reflux for 20 hours
3. 3
   ДругоеEvaporated
4. 4
   workup.ADDITIONwater (20 ml) added
5. 5
   Экстракцияextracted with diethyl ether (20 ml)
6. 6
   ДругоеThe extracts were dried
7. 7
   Фильтрацияfiltered
8. 8
   Другоеevaporated to a pale yellow liquid (5.5 g)
9. 9
   workup.DISTILLATIONDistilled

Методика

A mixture of 8-phenyloctyl chloride (4.4 g), sodium iodide (5.34 g) and acetone (20 ml) was heated under reflux for 20 hours. Evaporated, water (20 ml) added and extracted with diethyl ether (20 ml). The extracts were dried, filtered and evaporated to a pale yellow liquid (5.5 g). Distilled to give 8-phenyloctyl iodide, b.p. 200° C. (air bath temperature) at 0.1 mBar.

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