Реакция #502064

ord-7e11e4253b7d44f2a2c4ac9c3e72ef63

Уравнение реакции

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide
→
O=S(=O)([O-])CS(=O)(=O)[O-].[Ag+2]
silver methanedisulfonate
Выход 123.7%

Реактанты

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide

Реагенты

Нет

Растворители

O
water

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    Другоеany remaining insoluble material was removed by filtration
  2. 2
    Другоеwas removed under vacuum

Методика

Silver carbonate (20 g, 0.0725 moles) was added to methanedisulfonic acid (25.55 g 50% solution in water) and diluted in 25 mL of distilled water while stirring. The silver carbonate dissolved with effervescence of carbon dioxide. After the reaction was complete, any remaining insoluble material was removed by filtration and the filtrate was stripped of water was removed under vacuum to give 25.3 g of pure silver methanedisulfonate.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US08088548B2uspto-grants-2012_01