Реакция #502059

ord-11d94e99141441139220eea2e5013c4c

Уравнение реакции

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen
→
CC(C)CCCC(C)CCCC(C)CCCC(C)CCO
phytanol

Реактанты

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen

Реагенты

[Ni]
Raney nickel

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Методика

Hydrogenation of phytol can also be accomplished using Raney nickel and hydrogen to yield phytanol as referenced in Bendavid, A., Burns, C. J., Leslie, D. F., Hashimoto, K., Ridley, D. D., Sandanayake, S., and Wieczorek L., J. Org. Chem. (2001), 66, 3709-3716; Kim, T., Chan, K. C, and Crooks, R. M., J. Am. Chem. Soc. (1997) 119, 189; and Jellum, E., Eldjarn, L., and Try, K., Acta Chem. Scand. (1966), 20, 2335.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US08088395B2uspto-grants-2012_01