Реакция #487490

Уравнение реакции

phenoxyethyl methacrylate

methacrylic acid

methyl methacrylate

→

phenoxyethyl methacrylate methyl methacrylate methacrylic acid

Выход 162.8%

Растворители

methyl ethyl ketone

methyl ethyl ketone

methyl ethyl ketone

Условия реакции

Обработка

1. 1
   Другоеequipped with a stirrer and a condenser tube
2. 2
   ДругоеThen, a solution obtained
3. 3
   workup.ADDITIONwas added
4. 4
   workup.ADDITIONAfter the addition
5. 5
   Другоеto react for one hour
6. 6
   Другоеa solution obtained
7. 7
   workup.ADDITIONwas added
8. 8
   Другоеwas elevated to 78° C.
9. 9
   Температураthe mixture was heated for 4 hours
10. 10
    ДругоеThe obtained reaction liquid
11. 11
    Другоеwas reprecipitated twice with an excess of hexane
12. 12
    ДругоеThe separated resin was dried

Методика

88 g of methyl ethyl ketone was placed in a 1000 mL three-necked flask equipped with a stirrer and a condenser tube, and was heated to 72° C. under a nitrogen atmosphere. Then, a solution obtained by dissolving 0.85 g of dimethyl 2,2′-azobisisobutyrate, 50 g of phenoxyethyl methacrylate, 13 g of methacrylic acid, and 37 g of methyl methacrylate in 50 g of methyl ethyl ketone was added thereto dropwise over 3 hours. After the addition was completed, the mixture was further allowed to react for one hour, and then a solution obtained by dissolving 0.42 g of dimethyl 2,2′-azobisisobutyrate in 2 g of methyl ethyl ketone was added thereto. The temperature of the resulting mixture was elevated to 78° C., and the mixture was heated for 4 hours. The obtained reaction liquid was reprecipitated twice with an excess of hexane. The separated resin was dried, to obtain 96.5 g of a phenoxyethyl methacrylate/methyl methacrylate/methacrylic acid (copolymerization ratio [mass % ratio]=50/37/13) copolymer (polymer dispersant P-1).

Источник