Реакция #46027

ord-a14edf286595459bbce8fa7caecbf265

Уравнение реакции

CCCCCCCCCCCCCCCCCCCCCC(=O)OCCO
Ethylene glycol monobehenate
CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC
Distearylamine
CCCCCCCC/C=C\CCCCCCCC(=O)OCC(CO)(CO)CO
Pentaerythritol monooleate
CCCCCCCCCCCCCCCCCCO
Stearyl alcohol
CCCCCCCC/C=C\CCCCCCCC(=O)O
Oleic acid
CCCCCCCCCCCCO
Lauryl alcohol
CCCCCCCCCCCCCCCCCCO
Stearyl alcohol
OC[C@H]1O[C@@H](OC/C=C/c2ccccc2)[C@H](O)[C@@H](O)[C@@H]1O
Rosin

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Методика

Details of the (A), (B) and (C) components in Table 1, Table 1-2, Table 2, and Table-3 are as follows: (A) Component A-1: Pentaerythritol stearate (average ester replacement degree 45% by equivalent), A-2: Long chain fatty acid polyamide polyamine (MW=3,000 to 4,000); obtained by dropwise adding epichlorohydrin (1/3 mole ratio) to a compound obtained by reaction of polyethylene imine (MW=1,000) and Lunac S-40 (1/7 mole ratio) manufactured by Kao Corporation, A-3: Distearylamine, A-4: Ethylene glycol monobehenate, A-5: Pentaerythritol monooleate (average ester replacement degree 45% by equivalent), A-6: Stearyl alcohol PO adduct (PO=10 mole), A-7: Oleic acid, A-8: Beef tallow, A-9: Cured castor oil, A-10: Lauryl alcohol EO Adduct (EO=15 mole), A-11: Stearyl alcohol EO/PO adduct (EO 24/PO 18 random adduct), A-12: KB-115 (manufactured by Kao Corporation) (main component: fatty acid polyhydric alcohol ester), A-13: Rosin (Hartall R-WW, manufactured by Harima Chemicals, Inc.), A-14: Alkyl ketene dimer obtained by de-hydrochloric acid reaction, in the presence of ternary amine catalyst, of fatty acid chloride obtained by the reaction of phosphoric acid trichloride with Lunac S-40 (manufactured by Kao Corporation), A-15: Alkenyl succinic acid anhydride obtained by addition reaction of Dialen 168 manufactured by Mitsubishi Chemical Industries Ltd. and maleic anhydride at 3/2 mole ratio, and A-16: Methylpolysiloxane (KF96A-1000, manufactured by Shin-Etsu Silicone Co., Ltd.).

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US07740742B2uspto-grants-2010_06