Реакция #42645

ord-a7ccec1e0ec84f30a1458602cad251e8

Уравнение реакции

CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.[I-].[I-].[I-]
3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide
CNC.Cl
dimethylamine hydrochloride
→
CCCN(CCC)c1ccc2nc3ccc(N(C)C)cc3[s+]c2c1.[I-]
3-(N,N-dimethylamino)-7-(N,N-dipropylamino)-phenothiazin-5-ium iodide

Реактанты

CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.[I-].[I-].[I-]
3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide
CNC.Cl
dimethylamine hydrochloride

Реагенты

Нет

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    ДругоеThis compound was obtained
  2. 2
    ДругоеPrecipitation from dichloromethane
  3. 3
    workup.ADDITIONby addition of diethyl ether yielded purple lustrous crystals

Методика

This compound was obtained following isolation of 3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide and subsequent treatment with dimethylamine hydrochloride. Precipitation from dichloromethane by addition of diethyl ether yielded purple lustrous crystals. Mass spectrometry: C20H26N3OS requires m/z=340; found m/z=340 (I− not detected by mass spectrometry).

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US07732439B2uspto-grants-2010_06