Реакция #367323

ord-12e6596a3480404a82fdef258c893810

Уравнение реакции

O
water
O=[N+]([O-])c1ccc(O)cc1
p-nitrophenol
BrCC=CCBr
1,4-dibromo-2-butene
O=C([O-])[O-].[K+].[K+]
K2CO3
→
O=[N+]([O-])c1ccc(OCC=CCOc2ccc([N+](=O)[O-])cc2)cc1
1,4-Bis-(4-nitrophenoxy)-2-butene

Реактанты

O
water
O=[N+]([O-])c1ccc(O)cc1
p-nitrophenol
BrCC=CCBr
1,4-dibromo-2-butene
O=C([O-])[O-].[K+].[K+]
K2CO3

Реагенты

Нет

Растворители

CC(C)=O
acetone

Условия реакции

Температура
60°CELSIUS
Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    Фильтрацияfiltered
  2. 2
    Другоеto give
  3. 3
    Другоеafter drying

Методика

A mixture of 5.6 g of p-nitrophenol, 4.3 g of 1,4-dibromo-2-butene, and 5.6 g of K2CO3 in 80 ml of acetone was heated at 60° C. overnight. The reaction mixture was poured into water and filtered to give, after drying, 6.8 g of product as a creamy colored solid.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US04588737uspto-grants-1986_05