Реакция #334890

ord-9818f2d440c94e66beb956e8c8d5c486

Уравнение реакции

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
Выход 92.5%
O=C=O
carbon dioxide
Выход 26.9%

Реактанты

Реагенты

Растворители

Условия реакции

Температура
135°CELSIUS
Подробные условия
See reaction.notes.procedure_details.

Методика

A 100:1 mole ratio of ethylene carbonate:monoethylene glycol is heated with stirring under a nitrogen atmosphere for 121 hours at 135° C. using 0.1 percent Na2SnO3.3H2O as catalyst to give 92.5 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 26.9 percent carbon dioxide.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US04709069uspto-grants-1987_11