Реакция #334889

ord-2c5f41d7c6974a6e82f3a5e8b4cec75f

Уравнение реакции

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
Выход 96.6%
O=C=O
carbon dioxide
Выход 27.6%

Реактанты

Реагенты

Растворители

Условия реакции

Температура
135°CELSIUS
Подробные условия
See reaction.notes.procedure_details.

Методика

A 50:1 mole ratio of ethylene carbonate:monoethylene glycol is heated with stirring under a nitrogen atmosphere for 88 hours at 135° C. using 0.2 percent Na2SnO3.3H2O as catalyst to give 96.6 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 27.6 percent carbon dioxide.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US04709069uspto-grants-1987_11