Реакция #2679

Уравнение реакции

HCl

1-bromodecane

magnesium

diethyl carbonate

→

tri-n-decylcarbinol

Растворители

ethyl ether

ethyl ether

Условия реакции

Обработка

1. 1
   СушкаThe organic layer was dried with magnesium sulfate
2. 2
   Другоеthe ethyl ether evaporated off

Методика

Three moles of 1-bromodecane was slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether was slowly added to the mixture. After stirring for one hour at 30° C., the mixture was slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer was dried with magnesium sulfate and the ethyl ether evaporated off to give tri-n-decylcarbinol.

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