Реакция #2460328

Уравнение реакции

10-(4-butylphenyl)-10H-phenothiazine

diphenyliodonium hexafluorophosphate

→

10-(4-butylphenyl)-5-phenyl-10H-phenothiazin-5-ium hexa-fluorophosphate

Растворители

ether

Условия реакции

Обработка

1. 1
   ТемператураUpon cooling to ambient temperature
2. 2
   workup.ADDITIONwas added
3. 3
   Промывкаwashed with ether
4. 4
   Фильтрацияcollected by filtration
5. 5
   Промывкаwashed three times with ether
6. 6
   ДругоеWithout further purification
7. 7
   Другоеit was isolated in 98.2% (2.36 g)
8. 8
   Другоеyield as a pale yellow solid

Методика

A mixture of 10-(4-butylphenyl)-10H-phenothiazine (83) (1.44 g, 4.34 mmol), diphenyliodonium hexafluorophosphate (1.85 g, 4.34 mmol) and copper (I) benzoate (0.10 g) was heated at 120° C. for 3 hours under nitrogen. Upon cooling to ambient temperature, the mixture was transferred to a mortar-and-pestle and 50 ml of ether was added. The solid was finely powdered, washed with ether, collected by filtration and washed three times with ether. Without further purification, it was isolated in 98.2% (2.36 g) yield as a pale yellow solid.

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