Реакция #217455

Уравнение реакции

hydrochloric acid

2-Acetyl-7-hydroxyfluorene

allyl(4-chlorobutyl) ether

potassium carbonate

→

2-acetyl-7-(allyloxybutyloxy)fluorene

Выход 65.5%

Растворители

dimethylformamide

Условия реакции

Обработка

1. 1
   Другоеto obtain a solid matter
2. 2
   ФильтрацияThe solid matter was filtered
3. 3
   Другоеdried
4. 4
   Другоеit was recrystallized from ethanol

Методика

2-Acetyl-7-hydroxyfluorene 22.4 g, allyl(4-chlorobutyl) ether 18 g and potassium carbonate 20 g were added to dimethylformamide 150 ml and stirred at 90° C. for 8 hours. The reaction mixture was poured into 6N hydrochloric acid 300 ml to obtain a solid matter. The solid matter was filtered and dried, and then it was recrystallized from ethanol to obtain 22 g of 2-acetyl-7-(allyloxybutyloxy)fluorene. The melting point was 77° C.

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