Реакция #1747858

ord-2cce0eb6c5ba48c08bc7e0f8d9fcbd5f

Уравнение реакции

CN1c2ccc(-c3ccc4ccccc4c3)cc2S(=O)c2cc(-c3ccc4ccccc4c3)ccc21
10-methyl-3,7-bis(2-naphthyl)phenothiazine 5-oxide
O=C(OO)c1cccc(Cl)c1
m-chloroperbenzoic acid
CN1c2ccc(-c3ccc4ccccc4c3)cc2S(=O)(=O)c2cc(-c3ccc4ccccc4c3)ccc21
10-Methyl-3,7-bis(2-naphthyl)phenothiazine 5,5-dioxide

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Обработка

  1. 1
    ДругоеFor the preparation as a by-product
  2. 2
    Другоеwere obtained

Методика

For the preparation as a by-product in the synthesis of 10-methyl-3,7-bis(2-naphthyl)phenothiazine 5-oxide, see under Example 8. For a selective preparation of the sulfone, at least two molar equivalents of m-chloroperbenzoic acid are used. Yellowish microcrystals having a melting point of 328-332° C. were obtained.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US08029919B2uspto-grants-2011_10