Реакция #1486583

Уравнение реакции

3-methyl-1-phenyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide

lithium bis((trifluoromethyl)sulfonyl)amide

→

3-methyl-1-phenyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Выход 77.0%

Растворители

acetonitrile

Условия реакции

Обработка

1. 1
   ДругоеThe acetonitrile was removed under vacuum and water and DCM
2. 2
   workup.ADDITIONadded
3. 3
   ПромывкаThe organic layer was washed three times with water and brine
4. 4
   Другоеdried in vacuum at 110° C. for 48 hours

Методика

3-methyl-1-phenyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide and lithium bis((trifluoromethyl)sulfonyl)amide were mixed in acetonitrile and stirred overnight. The acetonitrile was removed under vacuum and water and DCM added. The organic layer was washed three times with water and brine and dried in vacuum at 110° C. for 48 hours, yielding 3-methyl-1-phenyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide. The following structure was confirmed:

Источник