Реакция #1328428

ord-50131e3760374c4f8fdf512b7a054219

Уравнение реакции

O=O
oxygen
Cc1ccc(C)cc1
p-xylene
CC(=O)ON1C(=O)c2ccccc2C1=O
N-acetoxyphthalimide
CC(=O)O
acetic acid
Cc1ccc(C(=O)O)cc1
p-toluic acid
O=C(O)c1ccc(C(=O)O)cc1
terephthalic acid

Условия реакции

Подробные условия
See reaction.notes.procedure_details.

Методика

A mixture of 2 mmol of p-xylene, 0.4 mmol of N-acetoxyphthalimide, 0.01 mmol of cobalt(II) acetate and 5 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 14 hours and thereby yielded terephthalic acid and p-toluic acid in yields of 91% and 1%, respectively.

Источник

DOI: 10.6084/m9.figshare.5104873.v1Патент: US07115541B2uspto-grants-2006_10