Реакция #1178402

Уравнение реакции

ortho-dichlorobenzene

Acecyclone

4-biphenylacetylene

methanol

→

8-[1,1′-Biphenyl]-4-yl-7,10-diphenylfluoranthene

Условия реакции

Обработка

1. 1
   ТемператураThe reaction was then cooled
2. 2
   ФильтрацияThe resulting yellow solid was filtered off
3. 3
   Промывкаwashed well with methanol
4. 4
   Другоеdried
5. 5
   Другоеwas sublimed at 220° C.

Методика

Acecyclone (12 g, 33.6 mMole) and 4-biphenylacetylene (9.0 g, 50.5 mMole) were heated to gentle reflux in ortho-dichlorobenzene (100 ML) for 2 hours. The reaction was then cooled, treated with methanol (20 mL) and stirred at room temperature for 1 hour. The resulting yellow solid was filtered off, washed well with methanol and dried. Yield of product ETM1, 17.4 g. Before use in device fabrication, ETM1 was sublimed at 220° C./10−3 mm Hg.

Источник