Реакция #1061585

Уравнение реакции

bis(cyclopentadienyl)titanium dichloride

1-[3-(2,4-difluorophenyl)propyl]-1H-pyrrole

lithium diisopropylamide

→

orange glassy resin

Выход 37.2%

Bis(cyclopentadienyl)bis[2,6-difluoro-3-(3-(1H-pyrr-1-yl)propyl)phenyl]titanium

Выход 37.2%

Условия реакции

Обработка

1. 1
   ДругоеThe brown-orange oil is purified by means of flash chromatography

Методика

Analogously to Example 19, 2.5 g (0.010 mol) of bis(cyclopentadienyl)titanium dichloride and 4.9 g (0.022 mol) of 1-[3-(2,4-difluorophenyl)propyl]-1H-pyrrole are reacted with 0.022 mol of lithium diisopropylamide solution. The brown-orange oil is purified by means of flash chromatography using hexane/ethyl acetate (9:1) as solvent. 2.3 g of an orange glassy resin are obtained.

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