Реакция #1036

Уравнение реакции

1-chloro-1,2-dibromotrifluoroethane

1,1,2-trichlorotrifiuoroethane

vinylidene chloride

persulfate sodium formate

→

4-bromo-3-chloro-3,4,4-trifiuorobutanoic acid

3,4- dichloro-3,4,4-trifluorobutanoic acid

Растворители

DMF

Условия реакции

Методика

A one pot reaction of 1-chloro-1,2-dibromotrifluoroethane (VI) or 1,1,2-trichlorotrifiuoroethane (X) with vinylidene chloride in the presence of ammoninm persulfate/sodium formate/air in DMF to give 4-bromo-3-chloro-3,4,4-trifiuorobutanoic acid (VIII) or 3,4- dichloro-3,4,4-trifluorobutanoic acid (XI).

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