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42213

CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=C[C@H](O)[C@H]3[C@@H]4[C@@H]5C[C@@H]5C(=O)[C@@]4(C)CC[C@@H]32)C1
Reaction #93687
3β-(tert.-butyldimethylsilyloxy)-7β-hydroxy-15β,16β-methylene-5-androsten-17-one
Выход 78.9%DOI: 10.6084/m9.figshare.5104873.v1
CC12CCC3C(CC=C4CC(O[Si](C)(C)C(C)(C)C)CCC43C)C1CCC2=O
Reaction #282677
DOI: 10.1039/C8SC04228D
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #527909
3β-tert-butyldimethylsilyloxy-androst-5-en-17-one
Выход 93.1%DOI: 10.6084/m9.figshare.5104873.v1
CC[C@@H]1CC(=O)[C@@]2(C)CC[C@H]3[C@@H](CC=C4C[C@@H](O[Si](C)(C)C(C)(C)C)CC[C@@]43C)[C@H]12
Reaction #927367
15β-ethyl-3β-t-butyldimethylsilyloxy-androst-5-en-17-one
DOI: 10.6084/m9.figshare.5104873.v1
CC(=O)O.CC(C)(C)[Si](C)(C)OC1CC[C@@]2(CO)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #1477950
3-t-butyldimethylsiloxy-19-hydroxy-5-androsten-17-one acetate
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)OC1CC[C@@]2(CO)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]32)C1
Reaction #1477969
3-t-butyldimethylsiloxy-5-androsten-17β,19-diol
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #1576121
(3β)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-androst-5-en-17-one
Выход 90.3%DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #1687771
(3β)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-androst-5-en-17-one
Выход 90.3%DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=C[C@H](O)[C@H]3[C@@H]4[C@@H]5C[C@@H]5C(=O)[C@@]4(C)CC[C@@H]32)C1
Reaction #1736644
3β-(tert.-butyldimethylsilyloxy)-7β-hydroxy-15β,16β-methylene-5-androsten-17-one
Выход 78.9%DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #1825966
(3β)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-androst-5-en-17-one
Выход 90.3%DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)O[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #2314420
A2
Выход 88.3%DOI: 10.6084/m9.figshare.5104873.v1
C[C@H]1CC(=O)[C@@]2(C)CC[C@H]3[C@@H](CC=C4C[C@@H](O[Si](C)(C)C(C)(C)C)CC[C@@]43C)[C@H]12
Reaction #2314424
3β-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-15α-methylandrost-5-en-17-one
DOI: 10.6084/m9.figshare.5104873.v1
CC1CC(=O)C2(C)CCC3C(CC=C4CC(O[Si](C)(C)C(C)(C)C)CCC43C)C12
Reaction #2411351
DOI: 10.1039/C8SC04228D