반응 #997152

반응 방정식

sodium 2-(1-adamantanecarbonyloxy)-1,1-difluoro-ethanesulfonate

triphenylsulfonium chloride

→

compound

수율 85.0%

triphenylsulfonium 2-(1-adamantanecarbonyl-oxy)-1,1-difluoroethanesulfonate

수율 85.0%

용매

dichloromethane

반응 조건

후처리

1. 1
   기타The organic layer was separated
2. 2
   세척washed three times with 20 g of water
3. 3
   농축concentrated
4. 4
   workup.ADDITIONDiethyl ether was added to the residue for recrystallization

실험 절차

In 100 g of dichloromethane were dissolved 10 g (0.02 mole) of sodium 2-(1-adamantanecarbonyloxy)-1,1-difluoro-ethanesulfonate (purity 70%) and 50 g (0.02 mole) of a triphenylsulfonium chloride aqueous solution. The organic layer was separated, washed three times with 20 g of water, and concentrated. Diethyl ether was added to the residue for recrystallization, obtaining the target compound as white crystals. 10 g (yield 85%).

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