반응 #985327

ord-f07cb4c8e2b444a2ad2eedeaf712b641

반응 방정식

CNC(=O)Cn1cc(C(=O)C(F)(F)F)c2ccc(Cl)cc21
2-[6-Chloro-3-(2,2,2-trifluoro-acetyl)-indol-1-yl]-N-methyl-acetamide
C[Si](C)(C)[O-].[Na+]
sodium trimethylsilanolate
CNC(=O)Cn1cc(C(=O)O)c2ccc(Cl)cc21
title compound
CNC(=O)Cn1cc(C(=O)O)c2ccc(Cl)cc21
6-Chloro-1-methylcarbamoylmethyl-1H-indole-3-carboxylic acid

용매

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    농축the mixture was concentrated in vacuo
  2. 2
    기타purified by prep

실험 절차

2-[6-Chloro-3-(2,2,2-trifluoro-acetyl)-indol-1-yl]-N-methyl-acetamide was suspended in DCE and treated with (2.2 eq.) of sodium trimethylsilanolate. After shaking at room temperature for 20 min, the mixture was concentrated in vacuo and purified by prep. HPLC to give the title compound.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07351706B2uspto-grants-2008_04