반응 #978030

반응 방정식

N-benzylidene aniline

gamma-aminopropyltrimethoxysilane

Silane

→

N-(phenylmethylene)-3-(trimethoxysilyl)-1-propanamine

용매

xylene

반응 조건

후처리

1. 1
   workup.DISTILLATIONDistillation of the xylene and aniline
2. 2
   기타resulted in 36 grams (98%) of N-benzylidene aminopropyltrimethoxysilane [cas no

실험 절차

25 grams (0.138 moles) of N-benzylidene aniline [cas no. 538-51-2, from TCI America] was combined with 24.7 grams (0.138 moles) of gamma-aminopropyltrimethoxysilane [cas no. 13822-56-5, Silquest A-1110 Silane from Crompton Corporation] and 100 grams of xylene. The resulting slurry was warmed to 90° C. for one hour before a vacuum of 20 mm Hg was applied. Distillation of the xylene and aniline resulted in 36 grams (98%) of N-benzylidene aminopropyltrimethoxysilane [cas no. 67674-55-9] by GC analysis.

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