반응 #95320

반응 방정식

hydrogen peroxide

tetrachloroacetone

cyclooctene

chloroform

→

cyclooctene oxide

수율 83.0%

용매

water

반응 조건

후처리

1. 1
   기타Water was removed continuously as it
2. 2
   기타was formed, over a period of 4 hours
3. 3
   온도of heating
4. 4
   기타The organic phase was then separated from the aqueous phase

실험 절차

There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis there was obtained an 83% yield of cyclooctene oxide.

출처