반응 #952967

반응 방정식

potassium carbonate

compound 25

1-tert-butyloxy-2,3-di(2-n-butoxy ethoxy)propane

dichloromethane

→

Compound 31

2,3-di-(2-n-butoxy ethoxy)propanol

용매

diethyl ether

반응 조건

후처리

1. 1
   기타The final yield

실험 절차

Compound 31 was prepared as described for 29. The reagents used were as follows, compound 25 (38.0 g, 0.109 mol.), tetrafluoroboric acid-diethyl ether complex (22 ml of a 54% solution in diethyl ether) dichloromethane (100 ml) and excess potassium carbonate. The final yield was a colorless liquid (17.3 g, 59%), (bpt. 95°-120° C., 0.04 torr): 1H-NMR (CDCl3), d, (ppm). Mass spectroscopy, m/e 293 MH+.

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