반응 #94484

반응 방정식

Ammonium

N-(3,4-dichlorostyrylsulfonyl)-3,4-dimethoxybenzimidoyl chloride

→

N-(3,4-DICHLOROSTYRYLSULFONYL)-3,4-DIMETHOXYBENZAMIDINE

수율 96.0%

용매

benzene

반응 조건

후처리

1. 1
   기타The solvent evaporated under reduced pressure
2. 2
   여과of water and filtered
3. 3
   기타affords 8.0 g

실험 절차

Ammonium gas is bubbled through a solution of N-(3,4-dichlorostyrylsulfonyl)-3,4-dimethoxybenzimidoyl chloride (8.7 g., 0.02 mole) in 100 ml. of dry benzene for a period of 1 hr. The solvent evaporated under reduced pressure and the solid residue stirred with 50 ml. of water and filtered affords 8.0 g. (96% yield) of N-(3,4-DICHLOROSTYRYLSULFONYL)-3,4-DIMETHOXYBENZAMIDINE, m.p. 205°-210° C. A sample crystallized from acetonitrile has a melting point of 208°-211° C.

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