반응 #94285

ord-afaf807a19e14d4ba6b67437a2a92448

반응 방정식

CCOC(=O)c1cn(CC)c2nc(Cl)ncc2c1=O
2-chloro-5-oxo-6-carbethoxy-8-ethyl-5,8-dihydropyrido(2,3-d)pyrimidine
CCCN1CCNCC1
1-propyl-piperazine
CCCN1CCN(c2ncc3c(=O)c(C(=O)OCC)cn(CC)c3n2)CC1
2-(4'-propylpiperazino)-5-oxo-6-carbethoxy-8-ethyl-5,8-dihydro-pyrido(2,3-d)pyrimidine
수율 84.6%

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

As described in Example XII, the condensation of 2.8 g of 2-chloro-5-oxo-6-carbethoxy-8-ethyl-5,8-dihydropyrido(2,3-d)pyrimidine with 2.2 g of 1-propyl-piperazine, in chloroform (40 cm3) gives, after the treatments described in Example XII, 3.14 g of 2-(4'-propylpiperazino)-5-oxo-6-carbethoxy-8-ethyl-5,8-dihydro-pyrido(2,3-d)pyrimidine (yield 84%); melting point 149° C., after recrystallisation from ethyl acetate.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04129737uspto-grants-1978_12