반응 #94175
ord-7416d7d0aa9c479f96b66490aae223e8
반응 방정식
용매
반응 조건
상세 조건
See reaction.notes.procedure_details.
후처리
- 1기타The resulting reaction mixture
- 2기타(theory, 10.0g.) of white solid, m.p. 94°-106° C. (decomp.) was obtained
실험 절차
To a vigorously stirred solution of 2.0 g. (0.029 mole) of 50% H2O2 and 25.2 g. (0.063 mole) of aqueous 10% sodium hydroxide at 10°-14° C. was added slowly 10.9 g. (0.0483 mole) of 3-(p-tolyloxycarbonyl)propionyl chloride in ether solution. The resulting reaction mixture was stirred for an additional 3 hours. After a work-up similar to that in Example I 9.1 g. (theory, 10.0g.) of white solid, m.p. 94°-106° C. (decomp.) was obtained. The assay according to "active oxygen" content was 92.3% and the corrected yield was 83.9%.