반응 #93935

반응 방정식

2-hydroxyethyl acrylate

dodecyl acrylate

→

2-hydroxyethyl acrylate dodecyl acrylate

수율 95.0%

용매

methyl ethyl ketone

반응 조건

후처리

1. 1
   기타To the solution obtained
2. 2
   온도The reaction mixture was maintained for 5 hours
3. 3
   workup.DISTILLATIONthe solvent was distilled off
4. 4
   세척the reaction product was washed several times with methanol

실험 절차

11.6 gm (0.1 mole) of 2-hydroxyethyl acrylate and 144 gm (0.6 mole) of dodecyl acrylate were dissolved in 360 gm of methyl ethyl ketone. To the solution obtained were added 3.1 gm of dibenzoyl peroxide as a catalyst. The reaction mixture was maintained for 5 hours under stirring at a temperature of 80° C. After the reaction was completed, the solvent was distilled off and the reaction product was washed several times with methanol. 148 gm, (95% of theory) of 2-hydroxyethyl acrylate/dodecyl acrylate copolymer (1:6 molar ratio) were obtained.

출처