반응 #93786

반응 방정식

allyl chloride

Me2SiHCl

Cl3SiH

→

Cl3SiCH2CH2CH2Cl

수율 60.4%

Me2SiClCH2CH2CH2Cl

수율 8.6%

반응 조건

후처리

1. 1
   기타an exothermic reaction to 47° C. in 7 min
2. 2
   기타VPC analysis 14 min.
3. 3
   기타a complete reaction
4. 4
   workup.DISTILLATIONVacuum distillation

실험 절차

In a 100 ml apparatus, there were combined 7.1 g (0.075 mol) of Me2SiHCl, 10.2 g (0.075 mol) of Cl3SiH, and 5.7 g (0.075 mol) of allyl chloride. Pt catalyst solution (0.01 ml) was added at 33° C., causing an exothermic reaction to 47° C. in 7 min. VPC analysis 14 min. later showed a complete reaction. Vacuum distillation yielded 60.4% Cl3SiCH2CH2CH2Cl and 8.6% Me2SiClCH2CH2CH2Cl. This example shows that Me2SiHCl is an effective promoter for the reaction of Cl3SiH with allyl chloride at the equimolar level.

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