반응 #93704

ord-18c892d44946454b87745d85f30ded14

반응 방정식

OC[C@H]1O[C@H](OC[C@H]2O[C@H](O[C@]3(CO)O[C@H](CO)[C@@H](O)[C@@H]3O)[C@H](O)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@H]1O
raffinose
OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
sucrose
→
CCCCCCCC/C=C\CCCCCCCC(=O)[O-].OC[C@H]1O[C@H](OC[C@H]2O[C@H](O[C@]3(CO)O[C@H](CO)[C@@H](O)[C@@H]3O)[C@H](O)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@H]1O
raffinose oleate
수율 85.2%

반응물

OC[C@H]1O[C@H](OC[C@H]2O[C@H](O[C@]3(CO)O[C@H](CO)[C@@H](O)[C@@H]3O)[C@H](O)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@H]1O
raffinose
OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
sucrose

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The procedure of Example 1 was repeated except that 10.08 g of raffinose was substituted for 3.4 g of sucrose. 6.65 g of raffinose oleate was obtained.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04614718uspto-grants-1986_09