반응 #93412

반응 방정식

benzoyl chloride

dimethyl carbonate

→

methyl benzoate

수율 70.1%

용매

sulfolane

반응 조건

후처리

1. 1
   workup.DISTILLATIONDistillation of the reaction mixture

실험 절차

The following example illustrates the use of alkali halide catalysts. A mixture of benzoyl chloride (7.03 g, 0.05 mole), dimethyl carbonate (4.5 g, 0.05 mole) and lithium chloride (0.106 g, 0.0025 mole) in 25 ml of sulfolane was heated to 150° C. for 22 hours. Distillation of the reaction mixture gave 4.77 g (70 percent yield) methyl benzoate.

출처