반응 #92826

반응 방정식

9-(4-bromophenyl)-10-phenylanthracene

3,6-bis(dibenzofuran-4-yl)-9H-carbazole

sodium tert-butoxide

tri(tert-butyl)phosphine

→

3,6-Bis(dibenzofuran-4-yl)-9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole

수율 59.0%

용매

toluene

hexane

toluene

반응 조건

후처리

1. 1
   기타This mixture was degassed
2. 2
   workup.STIRRINGThis mixture was stirred at 110° C. for 20 hours under a nitrogen stream
3. 3
   여과the mixture was suction-filtered through Celite (produced by Wako Pure Chemical Industries, Ltd., Catalog No. 531-16855), alumina, and Florisil (produced by Wako Pure Chemical Industries, Ltd., Catalog No. 540-00135)
4. 4
   기타The oily substance obtained by concentration of the filtrate
5. 5
   기타was recrystallized from toluene/hexane, so that 1.2 g of a yellow solid
6. 6
   기타was obtained in 59% yield
7. 7
   기타The synthesis scheme of Step 2

실험 절차

To a 100-mL three-neck flask were added 0.99 g (2.4 mmol) of 9-(4-bromophenyl)-10-phenylanthracene, 1.2 g (2.4 mmol) of 3,6-bis(dibenzofuran-4-yl)-9H-carbazole, and 0.62 g (6.4 mmol) of sodium tert-butoxide. After the air in the flask was replaced with nitrogen, to this mixture were added 20 mL of toluene and 0.2 mL of tri(tert-butyl)phosphine (a 10 wt % hexane solution). This mixture was degassed by being stirred while the pressure was reduced. After the degassing, 62 mg (0.11 mmol) of bis(dibenzylideneacetone)palladium(0) was added to the mixture. This mixture was stirred at 110° C. for 20 hours under a nitrogen stream. After the stirring, 100 mL of toluene was added to the obtained mixture, and the mixture was suction-filtered through Celite (produced by Wako Pure Chemical Industries, Ltd., Catalog No. 531-16855), alumina, and Florisil (produced by Wako Pure Chemical Industries, Ltd., Catalog No. 540-00135). The oily substance obtained by concentration of the filtrate was recrystallized from toluene/hexane, so that 1.2 g of a yellow solid was obtained in 59% yield. The synthesis scheme of Step 2 is illustrated in (b-8).

출처