반응 #88877

ord-0a27b93eed6d40d1858e2eaa50c774b8

용매

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    추출the mixture was extracted with ethyl acetate
  2. 2
    세척The extract was washed with saturated brine
  3. 3
    건조dried over anhydrous sodium sulfate
  4. 4
    여과filtered through basic silica gel
  5. 5
    농축The filtrate was concentrated under reduced pressure

실험 절차

A suspension of 2-chloronicotinic acid (0.20 g), 4-(4-cyanobenzyl)-4-hydroxypiperidine hydrochloride (0.32 g), HATU (0.72 g) and triethylamine (0.89 mL) in DMF (4.0 mL) was stirred overnight at room temperature. The reaction mixture was diluted with water, and the mixture was extracted with ethyl acetate. The extract was washed with saturated brine, and dried over anhydrous sodium sulfate, and filtered through basic silica gel. The filtrate was concentrated under reduced pressure to give the title compound (0.45 g).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US09440990B2uspto-grants-2016_09