반응 #86345

ord-e838596aa06443cf9285349e5594f4ae

용매

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타The crude reaction mixture
  2. 2
    세척washed with brine
  3. 3
    건조dried over Na2SO4
  4. 4
    농축concentrated by rotary evaporation

실험 절차

To 5-bromo-6-methyl-2-(methylamino)nicotinic acid (0.2 g, 0.816 mmol) in DMF (3 mL) were added azetidin-3-ol (0.119 g, 1.632 mmol), HOBt (0.154 g, 1.143 mmol), and EDC (0.235 g, 1.224 mmol), followed by N-ethyl-N-isopropylpropan-2-amine (0.426 mL, 2.448 mmol). The reaction mixture was stirred for 18 hours at room temperature. The crude reaction mixture was subsequently diluted with EtOAc, washed with brine, dried over Na2SO4, and concentrated by rotary evaporation to give the title compound, which was used without further purification (0.15 g).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US09434743B2uspto-grants-2016_09