반응 #85364

ord-1b545da8c99e48168a5e6e8338644669

반응 방정식

[I-]
iodide
[I-].[K+]
potassium iodide
CCN(C(C)=O)c1cn(-c2cccnc2)nc1Cl
N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethylacetamide
CC(=O)Nc1cn(-c2cccnc2)nc1Cl
1c
CC(=O)Nc1cn(-c2cccnc2)nc1Cl
N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)acetamide
Cl
hydrochloric acid
CCBr
ethyl bromide
CCNC1(Cl)C=CN(c2cccnc2)N1
3-chloro-N-ethyl-1-(pyridin-3-yl)-1H-pyrazol-amine

용매

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타necessary for the reaction
  2. 2
    온도that heating
  3. 3
    기타to about 24 hours

실험 절차

3-Chloro-N-ethyl-1-(pyridin-3-yl)-1H-pyrazol-amine (1d) may be prepared through the reaction pathway sequence disclosed in Scheme 3. In step d1, N-(3-chlorol-(pyridin-3-yl)-1H-pyrazol-4-yl)acetamide (1c) may be alkylated with ethyl bromide (EtBr) in the presence of a base, such as sodium hydride (NaH), sodium tert-butoxide (NaOt-Bu), potassium tert-butoxide (KOt-Bu), or sodium tert-amyloxide, in a polar aprotic solvent, such as tetrahydrofuran, at temperatures from about 20° C. to about 40° C., over a period of time of about 60 hours to about 168 hours, to yield N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethylacetamide (1c′). It has been discovered that use of an iodide additive, such as potassium iodide (KI) or tetrabutylammonium iodide (TBAI) can decrease the time necessary for the reaction to occur to about 24 hours. It has also been discovered that heating the reaction at about 50° C. to about 70° C. in a sealed reactor (to prevent loss of ethyl bromide) also decreases the reaction time to about 24 hours. In step d2, N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethylacetamide (1c′) may be treated with hydrochloric acid in water at temperatures from about 50° C. to about 90° C., to yield 3-chloro-N-ethyl-1-(pyridin-3-yl)-1H-pyrazol-amine (1d). The reaction pathway sequence disclosed in Scheme 3 may also be performed without the isolation of N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethylacetamide (1c′).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US09434712B2uspto-grants-2016_09