반응 #852

반응 방정식

p-Phenylenediamine

benzylisothiocyanate

→

colorless crystal

수율 61.6%

1,4-di(benzylthiocarbamoylamino)benzene

수율 61.6%

용매

ethyl acetate

반응 조건

후처리

1. 1
   온도After cooling
2. 2
   여과the reaction mixture was filtered
3. 3
   세척washed with ethylacetate/n-hexane

실험 절차

p-Phenylenediamine (2.707 g, 25 mM) was dissolved in 20 ml of ethyl acetate, and 2 equivalents of benzylisothiocyanate (7.461 g, 50 mM) were added. The mixture was stirred at 80° C. for 30 minutes. After cooling, the reaction mixture was filtered, and washed with ethylacetate/n-hexane to obtain 6.26 g (61.6% yield) of a colorless crystal of compound A-25.

출처