반응 #8506

ord-dee3bbe8fbf245858780f3dd89a7ddd2

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

4-Hydroxymethylpyridine (20) (54.4 g, 0.50 mol) was dissolved in acetonitrile 202 ml. The solution was added dropwise to a mixture of thionyl chloride (65.3 g, 0.55 mol) and acetonitrile (109 ml) under 50° C. The mixture was stirred at the same temperature for 1 hour, then cooled to room temperature to yield a slurry (quantitative) of the objective (21).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07087764B2uspto-grants-2006_08