반응 #81758

반응 방정식

2-methanesulfonyloxydecane

2,4,6-triiodophenol

potassium carbonate

2-(2,4,6-triiodophenoxy)-pentadecane

2-(2,4,6-triiodophenoxy)-pentadecane

→

2-(2,4,6-triiodophenoxy)-decane

수율 75.9%

용매

DMF

—

hexanes

반응 조건

후처리

1. 1
   기타to provide a light brown residue

실험 절차

The 2-methanesulfonyloxydecane (14.8 g, 62.6 mmol), 2,4,6-triiodophenol (29.7 g) 62.9 mmol) and potassium carbonate (8.7 g, 63.0 mmol) were reacted in DMF (210 ml) as per 2-(2,4,6-triiodophenoxy)-pentadecane except at an oil bath temperature of 72° C. for 88 hrs. The reaction was processed as for 2-(2,4,6-triiodophenoxy)-pentadecane to provide a light brown residue. Flash column chromatography (silica, hexanes) provided 2-(2,4,6-triiodophenoxy)-decane (29.1 g, 75.9%) as a white solid.

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