반응 #81382

ord-36461e8532db42809efa1d16c749e9dc

반응 방정식

O=S(=O)=O.c1ccncc1
sulfur trioxide pyridine
OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
sucrose
→
O=S(=O)(O)OC[C@H]1O[C@@](COS(=O)(=O)O)(O[C@H]2O[C@H](COS(=O)(=O)O)[C@@H](OS(=O)(=O)O)[C@H](OS(=O)(=O)O)[C@H]2OS(=O)(=O)O)[C@@H](OS(=O)(=O)O)[C@@H]1OS(=O)(=O)O
Sucrose octasulfate

반응물

O=S(=O)=O.c1ccncc1
sulfur trioxide pyridine
OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
sucrose

시약

없음

용매

O
water

반응 조건

온도
65°CELSIUS
상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타the substance was separated as a thick
  2. 2
    기타When the reaction was terminated
  3. 3
    기타the pyridine phase was decanted
  4. 4
    workup.DISSOLUTIONthe oily phase was dissolved in 600 ml of ion-exchanged water

실험 절차

254.7 g (1.6 mol) of sulfur trioxide pyridine were slurried in 1300 ml of water-free pyridine. With stirring, 68.5 g (0.2 mol) of sucrose were added. The reaction mixture was heated to 65° C. and kept at this temperature for 240 minutes. As the reaction proceeded, the substance was separated as a thick flowing oil. When the reaction was terminated, the agitator was stopped, the pyridine phase was decanted, and the oily phase was dissolved in 600 ml of ion-exchanged water.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05618798uspto-grants-1997_04