반응 #75415

ord-ffe7e54fd94245bcb5e2b8dde0e576d0

반응 방정식

CC(=O)SCC(CCC(O)C(C)C)C(=O)N1CCC[C@H]1C(=O)O
1-[2-(acetylthiomethyl)-5-hydroxy-6-methylheptanoyl]-L-proline
CSCC(CSC(C)=O)C(=O)N1CCC[C@H]1C(=O)O
1-[3-acetylthio-2-(methylthiomethyl)propanoyl]-L-proline
→
CC(C)C(O)CCC(CS)C(=O)N1CCC[C@H]1C(=O)O
1-[2-mercaptomethyl-5-hydroxy-6-methylheptanoyl]-L-proline

반응물

CC(=O)SCC(CCC(O)C(C)C)C(=O)N1CCC[C@H]1C(=O)O
1-[2-(acetylthiomethyl)-5-hydroxy-6-methylheptanoyl]-L-proline
CSCC(CSC(C)=O)C(=O)N1CCC[C@H]1C(=O)O
1-[3-acetylthio-2-(methylthiomethyl)propanoyl]-L-proline

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

By substituting 1-[2-(acetylthiomethyl)-5-hydroxy-6-methylheptanoyl]-L-proline for the 1-[3-acetylthio-2-(methylthiomethyl)propanoyl]-L-proline in the procedure of Example 17, 1-[2-mercaptomethyl-5-hydroxy-6-methylheptanoyl]-L-proline is obtained.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04176235uspto-grants-1979_11